Bis[N,N-bis(diphenylphosphanyl)cyclohexylamine-κ2 P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
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چکیده
In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P-Pt-P bite angle of 70.76 (3)°. The cyclo-hexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloro-methane solvent mol-ecule displays 0.526 (4):0.474 (4) positional disorder. C-H⋯F hydrogen bonds stabilize the crystal packing.
منابع مشابه
Bis[N,N-bis(diphenylphosphanyl)pentylamine-κ2 P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis-(di-phenyl-phosphan-yl)pentyl-amine ligands with an average Pt-P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P-Pt-P bite angles of 70.45 (3) and 70.64 (3)°. The asymmetric unit...
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